Physical Chemistry @ Stockton

All things relevant to Physical Chemistry I & II at Stockton.

Archive for March, 2009

Vibrational-rotational spectroscopy

Posted by richardm on 30th March 2009

Summary - Slides - Homework #7 Model Solutions

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Combining vibrations and rotations

Posted by richardm on 27th March 2009

We finished up our discussion of pure rotational spectroscopy and then began to discus the implications of combining vibrational and rotational transitions.

Summary - Slides

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The rigid rotor

Posted by richardm on 25th March 2009

We finished up our discussion of pure vibrational spectroscopy and began talking about rotations and the rigid rotor model.

Summary - Slides

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Modeling of vibrations with the harmonic and anharmonic oscillator

Posted by richardm on 23rd March 2009

We expanded on our model to include the asymmetry of the potential energy curve. We explored implications of the anharmonicity.

Summary - Slides - Homework 7

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Quantum mechanical harmonic oscillator

Posted by richardm on 13th March 2009

We began our discussion of vibrational spectroscopy by considering the quantum mechanical harmonic oscillator model for diatomic molecules.

Summary - Slides

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Molecular spectroscopy

Posted by richardm on 11th March 2009

After finishing up talking about solid state conductivity and extrinsic semiconductors we introduced molecular spectroscopy by exploring the different transitions possible moving from atoms to molecules.

Summary - Slides

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Polyatomic, conjugated molecules, and introduction to band theory

Posted by richardm on 9th March 2009

We finished up a discussion of polyatomic molecules and saw the connection between the PIB model and conjugated molecules. We then started to talk about solids and band structure.

Summary - Slides

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More on MO’s: more complicated molecules

Posted by richardm on 6th March 2009

We continued discussing molecular orbital theory and its application to more complex molecules. Exam 1 was returned and we discussed some of the more common mistakes. Model solutions are posted.

Summary - Slides - Homework 6

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Exam 1 Model Solutions

Posted by richardm on 5th March 2009

Model solutions for Exam 1 have been posted. Please take a look at them and come to class tomorrow with questions.

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Molecular orbitals and homonuclear diatomics

Posted by richardm on 4th March 2009

We put atomic orbitals together to make molecular orbitals. We spent a fair amount of time looking at the mathematics of adding these wavefunctions together and then explored their shapes, etc.

Summary - Slides

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