Physical Chemistry @ Stockton

All things relevant to Physical Chemistry I & II at Stockton.

Archive for November, 2009

Homework 9 Model Solutions

Posted by richardm on 24th November 2009

I have posted model solutions for Homework 9. Sorry for the delay.

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Polymerization

Posted by richardm on 20th November 2009

We discussed polymers as one example of chain reactions. We also began our discussion of catalysis.

Exam 3 (take-home) was also distributed. It is due at the beginning of class on Monday, November 30. It must be returned in person on that day. Late exams will not be accepted.

Summary - Slides

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Chain reactions

Posted by richardm on 18th November 2009

We explored chain reactions as an example of a more complex mechanism that can lead to some interesting rate laws and phenomena.

Summary - Slides

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Pre-equilibrium, competing reactions, and unimolecular reactions

Posted by richardm on 16th November 2009

We took a look at additional approximation methods to handle more complex mechanisms. The application to some organic systems was also discussed.

A new homework (Homework #9) was distributed and is due next Monday (11/23).

The third exam (take-home) will be distributed on Monday, 11/23 and will be due Monday 11/30.

Summary - Slides

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Mechanisms and the steady state approximation

Posted by richardm on 13th November 2009

Summary - Slides

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Reaction mechanisms

Posted by richardm on 11th November 2009

We looked at some examples of “simple” mechanisms. We explored the analytical solutions to the care of parallel reactions and began to discuss consecutive reactions. Exam 2 was returned and the solutions are posted on the course website.

Summary - Slides

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Integrated rate laws & introduction to mechanisms

Posted by richardm on 10th November 2009

We reviewed the use of integrated rate laws in determining rate expressions. We then turned our attention to mechanisms and elementary reactions.

Summary - Slides

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Introduction to Chemical Kinetics

Posted by richardm on 6th November 2009

After a summary of some overarching thermodynamics concepts, we began to discus chemical kinetics. We looked at several ways to write the rate of a chemical reaction and the associated rate law.

Summary - Slides

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Eutectic phase diagrams

Posted by richardm on 2nd November 2009

We explored a more complex binary system where the liquid is nearly ideal and there is limited solid solubility.

Exam 2 was also distributed. It is due in-class on Monday and must be returned in person.

Summary - Slides - Practice Problems

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